NETWORK ON

NANOMETER SIZE METAL COMPLEXES

 

 

 

PISA TMR WORKSHOP &emdash; Program

 

Scuola Normale Superiore, Piazza dei Cavalieri &emdash; Aula Bianchi

 

 

  • First day, Friday 22 September

     

    Session 1

     

    09:00 - 09:10 Welcome (Gianfranco Denti, Pisa)

    09:10 - 09:40 Tutorial 1 - Ru(II) complexes under visible illumination: from polynuclear species to supramolecular systems with DNA (Fanny Kirsch, Brussels).

    09:40 - 10:00 Lecture 1 - Towards Molecular Devices: From Multimetallic Complexes to Supramolecular Networks (Phil Mackie, Dublin)

    10:00 - 10:20 Lecture 2 - Stereospecific synthesis of novel polymetallic complexes based on Ru and Os. (Alain Maggiani, Pisa)

    10:20 - 10:40 Lecture 3 - Creating new binding sites in metal complexes (Garry Hanan, Waterloo).

     

     

    10:40 - 11:20 Coffee break

     

    Session 2

     

    11:20 - 11:50 Lecture 4 - Binuclear metal complexes and lifetime analysis of DNA-bound complexes (John Kelly, Dublin)

    11:50 - 12:20 Lecture 5 - Photophysical studies on the deuterated dppz compounds and the dppz rhenium tricarbonyl compounds (Carlos Penedo, Dublin)

    12:20 - 12:40 Lecture 6 - Ru derivatized oligonucleotides. Quenching processes by the complementary strands. Part I: Experimental aspects. (O. Lentzen, Brussels).

    12:40 - 13:00 Lecture 7 - Ru derivatized oligonucleotides. Quenching processes by the complementary strands. Part II: Theoretical results. (S. Schumm, Brussels).

     

     

    13:00 Lunch (refectory of Scuola Normale Superiore)

     

    Session 3

     

    15:00 - 15:30 Tutorial 2 - Chiragen Ligands (Alex Von Zelewsky, Fribourg)

    15:30 - 15:50 Lecture 8 - Polynuclear Ru(II) complexes with the PHEHAT and HATPHE ligand. From dinuclear to dendritic species. (Julien Leveque, Brussels)

    15:50 - 16:10 Lecture 9 &emdash; New homometallic dinuclear polypyridine complexes of Ir(III), Ru(II), and Os(II). (Frédérique Loiseau, Messina)

    16:10 - 16:30 Lecture 10 - Chiral Macrocycles (Sandrine Fraysse, Fribourg)

     

    16:30 -17:00 Coffee break

     

    Session 4

     

    17:00 - 17:20 Lecture 11 &emdash; New luminescent dendrons as efficient light-harvesting antennas (Fausto Puntoriero, Messina)

    17:20 - 17:40 Lecture 12 - Self-Assembled Chiral Coordination Compounds Starting from a new CHIRAGEN Family. (Marielle Loï, Fribourg)

    17:40 - 18:00 Lecture 13 - Studies by ESMS of the formation in solution of non-covalent complexes: Cis-platin selectivity for DNA. (Nathalie Carte, Strasbourg)

     

  •  

    20.00 Social Dinner at "Villa di Corliano"

     

     

     

     

     

  • Second day, Saturday 23 September

     

     

     

    09:00 - 10:20 Board meeting (team leaders and representatives)

     

     

    Session 5

     

    10:20 - 10:40 Lecture 14 - Studies by ESMS of the formation in solution of non-covalent complexes: Chiral recognition . (Hélène Nierengarten, Strasbourg).

    10:40 - 11.00 Lecture 15 - Oligopyridinyl-pyrazine Ligands for Self-Assembly: Formation of Circular Helicates and the Challenge of Predetermination of Metal-centred Chirality. (Thomas Bark, Fribourg)

     

     

    11:00 - 11:30 Coffee break

     

    Session 6

     

    11:30 - 12:00 Lecture 16 - Photochemical devices based on fullerene C60. (Nicola Armaroli, Bologna).

    12:00 - 12:20 Lecture 17 - From Mono- to Polynuclear Polypyridyl Complexes (Antonella Di Trapani, Dublin).

    12:20 - 12:40 Lecture 18 - New Chiragen Family Containing Metallocene as Bridges. (Boris Quinodoz, Fribourg)

    12:40 - 13:00 Lecture 19 - Towards novel metal-containing dendrimers decorated with bi-/trichromophoric ligands (Nathan McClenaghan, Messina)

     

     

    13:00 Lunch (refectory of Scuola Normale Superiore)

     

    Session 7

     

    15:00 - 15:30 Tutorial 4 - Control of photoinduced energy transfer between metal-polypyridyl units in rigid, flexible, and H-bonded systems. (Francesco Barigelletti, Bologna)

    15:30 - 15:50 Lecture 20 - Probing interaction with DNA: new optically pure Ru(II) complexes with a Troger's base skeleton. (Carole Bresson, Brussels).

    15:50 - 16:10 Lecture 21 - Effect of extended conjugation on metal-metal communication (Matthew Polson, Waterloo)

     

     

    16:10 - 16:40 Coffee break

     

    Session 8

     

    16:40 - 17:00 Lecture 22 - Protonation of Chiral Bipyridine Derivatives (Mathias Düggeli, Fribourg).

    17:00 - 17:20 Lecture 23 - Novel optically pure Rh(III) complexes. Their photophysical behaviour in the absence and presence of DNA. (André Brodkorb and Liana Ghisdavu, Brussels)

     

     

    17:20 -18:30 Overview and general discussion

    End of the workshop