Nanometer Size Metal Complexes
Fribourg, 20-21 February 1999
Saturday February 20
08:30, Chemistry Institute, Grand Auditoire.
Opening of the Workshop, AVZ
08:40 - 09:10 Sebastiano Campagna, Messina
"Metal Dendrimers as Artificial Antenna Systems"
09:10 - 09:30 Fanny Kirsch, Brussels
"Overview of the TMR research in Brussels"
09:30 - 10:00 John Kelly + Paul Kruger, Dublin
"Nanometer Scale Metallo-Based Assemblies: Their Chirality,
Interaction with DNA, Photophysics and Magnetic Properties"
10:00 - 10:30 Coffee Break
10:30 - 11:00 Lucia Flamigni/Francesco Barigelletti, Bologna
"Photoinduced processes in multicomponent systems"
11:00 - 11:20 Gianfranco Denti, Dr. Milena Sommovigo, Pisa
"Luminescent and Redox-active Oligonuclear Bi- and Trimetallic Complexes of Osmium, Rurenium and Platinum"
11:20 - 11:50 Alain Van Dorsselaer, Strasbourg
"MS and non-covalent interactions"
11:50 - 12:15 Alex von Zelewsky, Fribourg
"Chiral Building Blocks"
12:30 Lunch (in Chemistry Building)
13:30 - 14:00 Strasbourg group
Dr. Emmanuelle Leize
"MALDI-MS: a new tool for probing interactions between
proteins and metal surface. Use in dental implantology"
H. Nierengarten
"ESMS characterization of high-molecular-weight Cu(II)
coordination polymers"
14:00 - 15:15 Brussels group
A. Brodkorb: "Molecular recognition and photo-electron
transfer between stereoisomers of a dinuclear Ru(II)
complex and mono- and polynucleotides" (20-25)
J. Kolnaar: "Synthesis of dinuclear and dendritic Ru(II)
species based on the PHEHAT ligand" (20-25)
F. Piérard: "Use of Chiral building blocks in the stereo-
specific preparation of Ru(II) complexes containing a phenanthroline analogue of Tröger base as chiral ligand"
A. Etoc: "Design of new optically resolved complexes containing the ligand PHEHAT" (10)
15:15 - 15:45 Discussion
15:45 - 16:15 Susana Encinas (Bologna)
"Luminescent molecular wires with 2,5-thienyl spacers linking [Ru(tpy)2] and [Os(tpy)2] units"
16:15 - 16:45 Coffee break
16:45 - 17:00 Frédérique Loiseau (Messina)
"Synthesis and properties of Ru(II) and Os(II) building
blocks suitable to prepare larger polymetallic arrays
featuring specific functions
17:00 - 18:15 Dublin group
Dr. Philip R. Mackie
"Heterometallic Coordination Complexes with Novel Photophysical and Magnetic Properties"
Dr. Carlos Penedo-Esteiro
"Photophysical Investigation of RuII polypyridyls and DNA"
Antonella Di Trapani
"Chromium Coordination Complexes as Precursors to
Heterometallic Species"
Michelle E. Higgins
"Enantiomerically Pure Metal Complexes as Probes for DNA"
Karen OiDonoghue
"Binuclear Metal Complexes as DNA Probes"
18:15 - 18:45 Discussion
19:45 Dinner, Rest. Soleil Blanc
Sunday, February 21
09:00 - 10:00 Business meeting (Coordinator + Team leaders)
10:00 - 11:00 Fribourg group
Ulrich Knof
"Predetermination of Chirality at Chiral Metal Centers"
Gabriella Albano
"New luminescent Ruthenium-Complexes with extended
p systems"
Liana Ghizdavu
"Stereoselectivity and Transfer of Chirality in Rh(III) Complexes"
Olimpia Mamula
"From Circular Helicates to DNA like Structures"
Jorge Parola
"Towards Metal-Complexing Hemicarcerands"
11:00 - 12:00 General discussion.
Sunday after 12:00 ad hoc organization of activities. If needed, more scientific discussions, or some local excursions. Fribourg people will be available as guides.